过氧化氢法制备二氧化氯的反应机理及动力学作者：钱宇;陈赟;江燕斌;纪红兵作者机构：华南理工大学化工学院,广东,广州,510640;华南理工大学化工学院,广东,广州,510640;华南理工大学化工学院,广东,广州,510640;华南理工大学化工学院,广东,广州,510640来源：化工学报ISSN：0438-1157年：2004卷：055期：010页码：1719-1722页数：4中图分类：TQ033正文语种：chi关键词：过氧化氢;二氧化氯;清洁生产工艺;反应机理;动力学摘要：To develop a cleaner production process of H2O2-based chlorine dioxide, this paper presents a study on reaction mechanism and dynamics of the process. It is shown that a complex H2ClO2-ClO3 exists as an intermediate in the process. A rational reaction process is proposed, which unifies several reaction mechanisms reported by different researchers in a wider range of reaction temperature. A theoretical model of the dynamics is presented, and parameters of the model are experimentally estimated and verified.

过氧化氢法制备二氧化氯的反应机理及动力学